Download Organomagnesium Me...

Format: Hardcover

Language: English

Pages: 249

Publisher: Academic Press; 1 edition (April 26, 1995)

ISBN: 0127309454

Format: PDF / Kindle / ePub

Size: 9.1 MB

Downloadable formats: PDF


The e-book opens with a common assessment of the structure and reactivity of organomagnesium compounds, through details on dealing with them and on their detection and estimation. all through, functional features aswell as ideas are emphasized.The chapters at the synthesis of organomagnesium compounds hide the instruction of specific different types of steel magnesium and the response of magnesium with substrates equivalent to dienes, in addition to the conventional guidance of Grignard reagents. arrangements by means of metallation and metal-halogen exchanges also are incorporated, as are more recent tools equivalent to hydromagnesiation of alkenes and alkynes.Systematic insurance is supplied on synthetically worthwhile reactions of organomagnesium compounds. Of primary significance in natural synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur a number of bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in natural compounds is defined, the place the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. ultimately, using organomagnesium compounds in getting ready different organometalloid and organometallic compounds is outlined.Representative experimental strategies are incorporated during the publication, and tables with references to well-described examples are supplied. Key positive factors* provides a common evaluate of the structure and reactivity of organomagnesium compounds* presents insurance at the detection and estimation of organomagnesium compounds* Emphasizes useful features in addition to rules* Covers the guidance of distinct varieties of steel magnesium and the response of magnesium with substrates reminiscent of dienes* contains arrangements via metallation and metal-halogen exchanges* reports new training equipment comparable to hydromagnesiation of alkenes and alkynes* Outlines info on synthetically valuable reactions of organomagnesium compounds* Describes the formation of carbon-heteroatom bonds in natural compounds* Addresses using organomagnesium compounds in getting ready different organometalloid and organometallic compounds* comprises consultant strategies and tables with references to well-described examples

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